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堿性固體燃料電池堿性聚合物電解質(zhì)膜的最新研究進(jìn)展

發(fā)布時(shí)間:2019-01-16 08:52
【摘要】:最近,堿性聚合物電解質(zhì)膜燃料電池(APEMFC)因具有電極反應(yīng)動(dòng)力學(xué)快以及不依賴(lài)于貴金屬鉑催化劑等諸多優(yōu)點(diǎn)而成為一個(gè)熱門(mén)話題.作為其中一個(gè)關(guān)鍵部件,堿性聚合物電解質(zhì)膜直接影響燃料電池的性能和成本.然而,迄今為止,仍然沒(méi)有令人滿(mǎn)意的堿性電解質(zhì)膜材料.為此,大量研究被開(kāi)展和報(bào)道.本文綜述了近三年內(nèi)文獻(xiàn)中關(guān)于燃料電池堿性聚合物電解質(zhì)膜的最新研究進(jìn)展:包括各種各樣的合成策略,構(gòu)效關(guān)系,水管理以及非原位或原位穩(wěn)定性測(cè)試等等.尤其是一些新的金屬離子基陰離子交換膜和冠醚基陰離子交換膜首次被提及和評(píng)論.此外,還進(jìn)一步預(yù)測(cè)了將來(lái)的發(fā)展趨勢(shì).
[Abstract]:Recently, alkaline polymer electrolyte membrane fuel cell (APEMFC) has become a hot topic because of its advantages of fast electrode reaction kinetics and no dependence on noble metal platinum catalyst. As one of the key components, alkaline polymer electrolyte membrane directly affects the performance and cost of fuel cells. So far, however, there is still no satisfactory alkaline electrolyte membrane material. To this end, a large number of studies have been carried out and reported. In this paper, the latest research progress on basic polymer electrolyte membranes for fuel cells in recent three years is reviewed, including various synthesis strategies, structure-activity relationships, water management and non-in-situ or in-situ stability tests, etc. In particular, some new metal ion-base anion exchange membranes and crown ether based anion exchange membranes have been mentioned and reviewed for the first time. In addition, the future development trend is further predicted.
【作者單位】: 昆明理工大學(xué)材料科學(xué)與工程學(xué)院;
【基金】:supported by the National Natural Science Foundation of China (51363011) the 46th Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education, China (6488-20130039) Program of High-level Introduced Talent of Yunnan Provincein 2012, China (10978125) Yunnan Project of Training Talent, China (1418425) Project of Key Discipline, China (14078232)~~
【分類(lèi)號(hào)】:O646;TM911.4

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