硝酸侵蝕噴射混凝土耐久性能試驗研究
[Abstract]:The emission of automobile exhaust is increasing day by day, the nitrogen oxide in the tail gas is oxidized to nitric acid. It affects the durability of tunnel lining concrete structure, especially shotcrete monolayer permanent lining structure. The effect of nitrogen oxides in tail gas on durability of shotcrete was studied in this paper. In this paper, the long-term immersion test of nitric acid solution for shotcrete is carried out, and the deterioration law and mechanism of nitric acid erosive shotcrete are studied from three aspects: microscopic, mesoscopic and macroscopic. The mineral composition and morphology of shotcrete at different erosion times and pH values were analyzed by means of X-ray diffraction and scanning electron microscopy, and the process of nitric acid erosion was explained from the microscopic point of view. The erosion mechanism and microstructure of shotcrete caused by nitric acid are revealed. The alkalinity and nitrate mass percentage of shotcrete pore solution after erosion were tested, and the effects of soaking time and pH value on basicity and nitrate mass percentage of shotcrete were analyzed. The alkalinity of shotcrete after erosion and the mechanism of nitrate migration are obtained. The effects of immersion time, pH value of soaking solution and steel fiber content on mass loss rate, compressive strength, splitting tensile strength, thickness of damage layer and relative dynamic elastic modulus of shotcrete were studied. The calculation models of relative dynamic modulus of elasticity, compressive strength, splitting tensile strength and thickness of damage layer of concrete are established. The influence coefficient of steel fiber is introduced to study the changing process and law of compressive strength, splitting tensile strength and thickness of damage layer of steel fiber sprayed concrete. Based on the analysis of the basic properties of concrete and shotcrete specimens after nitric acid erosion, the difference of failure mechanism between them and their effects on durability were studied.
【學(xué)位授予單位】:西安建筑科技大學(xué)
【學(xué)位級別】:碩士
【學(xué)位授予年份】:2015
【分類號】:TU528
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