發(fā)布時(shí)間：2018-03-22 15:14

  本文選題：松花江　切入點(diǎn)：雌激素　出處：《哈爾濱工業(yè)大學(xué)》2014年碩士論文　論文類型：學(xué)位論文

【摘要】：雌激素和孕激素是重要的內(nèi)分泌干擾物，這類物質(zhì)在環(huán)境中極其微量的存在都有可能對生態(tài)系統(tǒng)及人類健康造成潛在危害。研究這類物質(zhì)在松花江哈爾濱段的分布情況，能夠幫助全面了解松花江的水質(zhì)狀況，為相關(guān)研究和決策提供數(shù)據(jù)支持。 本文利用在線固相萃取技術(shù)，建立了水中雌激素和孕激素類物質(zhì)的UPLC-MS/MS分析方法，該方法對各雌激素和孕激素的檢測限為0.1~1.0ng/L，滿足痕量分析的要求。 通過對松花江哈爾濱段的水體進(jìn)行采樣分析，發(fā)現(xiàn)該江段內(nèi)雌激素E1、E2、E3和EE2的濃度范圍分別為ND~25.5ng/L、 ND~9ng/L、 ND~19.5ng/L和ND~8.7ng/L，孕激素CPA、LNG的濃度范圍分別為ND~12.7ng/L、ND~3.4ng/L，孕激素GES在所有水樣中未檢出。雌激素和孕激素總濃度在該江段內(nèi)呈現(xiàn)江南高于江北，下游高于上游，冰雪消融期和豐水期高于枯水期的規(guī)律。在人類活動(dòng)比較集中的采樣點(diǎn)以及河溝匯入口下游的采樣點(diǎn)，雌激素和孕激素的濃度有所增加。通過對比E1和E2的濃度之比，推測水中雌激素的存在與人類的活動(dòng)有很大關(guān)系。 生態(tài)風(fēng)險(xiǎn)評價(jià)表明，松花江哈爾濱段的水體中E1、E2、E3和LNG的存在具有一定的生態(tài)風(fēng)險(xiǎn)，需要采取相關(guān)措施。雌激素活性分析同樣表明，該江段內(nèi)大部分采樣點(diǎn)的EEQ值高于預(yù)測無影響濃度，需要采取相關(guān)措施加以控制。 考察了水廠常規(guī)處理工藝以及給水深度處理中試系統(tǒng)對水中雌、孕激素類污染物質(zhì)的去除效果。結(jié)果表明，常規(guī)水處理單元對水中雌、孕激素的去除效果不佳�；炷恋韱卧獙Υ啤⒃屑に氐娜コ什坏�40%，過濾對雌、孕激素的去除率不到20%，且兩個(gè)單元都出現(xiàn)了出水濃度高于進(jìn)水的情況。 臭氧對雌、孕激素有很好的去除效果，且臭氧對雌、孕激素的去除效果與臭氧投量有關(guān)，也與雌、孕激素初始濃度有關(guān)。臭氧投量為1.5~3.0mg/L時(shí)，雌激素和孕激素的去除率為90%~97%。雌激素和孕激素初始濃度較低時(shí)，去除率略有下降。通過對臭氧氧化產(chǎn)物進(jìn)行分析，發(fā)現(xiàn)臭氧并沒有將目標(biāo)污染物完全礦化。 生物活性炭單元和超濾單元單獨(dú)使用時(shí)對水中雌、孕激素的去除率低于臭氧單元。其中生物活性炭單元對E2和E3的去除率在70%左右，對E1和EE2的去除率不到20%，超濾單元對各雌激素和孕激素的去除率在65%~85%之間。高級(jí)氧化—吸附—超濾膜過濾組合工藝對雌激素和孕激素具有很好的去除效果，出水中基本沒有檢出雌激素和孕激素，說明該工藝能很好地保證出水水質(zhì)。
[Abstract]:Estrogen and progesterone are important endocrine disruptors, and the presence of these substances in the environment may cause potential harm to ecosystem and human health. Can help to understand the water quality of Songhua River, and provide data support for related research and decision. An on-line solid phase extraction (SPE) method for the determination of estrogen and progesterone in water by UPLC-MS/MS has been developed. The detection limit of each estrogen and progesterone is 0.1 ~ 1.0ng / L, which meets the requirements of trace analysis. By sampling and analyzing the water body in Harbin section of Songhua River, It was found that the concentration range of estrogen E _ (1) E _ (2) E _ (2) E _ (3) and E _ (2) E _ (3) and E _ (2) E _ (3) and E _ (2) E _ (3) and E _ (2) E _ (2) E _ (3) and E _ (2) E _ (3) and E _ (2) E _ (3) and E _ (2) E _ (3) and E _ (2) E _ (3) and E _ (2) E _ (3) and E _ (2) E _ (2) E _ (3) and E _ (2) E _ (2) E _ (3) and E _ (2) N. The regularity that the downstream is higher than the upstream, and the ice and snow melting period and the high water season are higher than the dry season. The concentrations of estrogen and progesterone have been increased. By comparing the concentration of E1 and E2, it is inferred that the existence of estrogen in water is closely related to human activities. The ecological risk assessment shows that the existence of E1C E2E3 and LNG in Harbin section of Songhua River has certain ecological risks, and some relevant measures should be taken. The analysis of estrogenic activity also shows that E1C E2E3 and E2E3 in Harbin reach of Songhua River have some ecological risks. The EEQ value of most sampling points in this section is higher than that of predicted unaffected concentration, and relevant measures should be taken to control it. The removal efficiency of female and progesterone pollutants in water by conventional treatment process and advanced water treatment system was investigated. The removal rate of progesterone in coagulation sedimentation unit was less than 40% for female, and less than 20% for female in filtration, and the effluent concentration was higher than that in influent in both units. Ozone has a good effect on the removal of estrogen and progesterone, and the removal effect of ozone on estrogen and progesterone is related to the amount of ozone, and also to the initial concentration of estrogen and progesterone. The removal rate of estrogen and progesterone is 90%. When the initial concentration of estrogen and progesterone is low, the removal rate decreases slightly. Through the analysis of ozonation products, it is found that ozone does not completely mineralize the target pollutant. The removal rate of progesterone in water by biological activated carbon unit and ultrafiltration unit alone was lower than that of ozone unit, and the removal rate of E2 and E3 by biological activated carbon unit was about 70%. The removal rate of E1 and EE2 was less than 20%, and the removal rate of estrogen and progesterone by ultrafiltration unit was between 65% and 85%. Estrogen and progesterone were not detected in the effluent, indicating that the process can ensure the quality of the effluent.
【學(xué)位授予單位】：哈爾濱工業(yè)大學(xué)
【學(xué)位級(jí)別】：碩士
【學(xué)位授予年份】：2014
【分類號(hào)】：TU991.2;X143

【相似文獻(xiàn)】

相關(guān)期刊論文 前4條

1 方秋華;黃顯會(huì);郭春娜;楊剛;孔祥凱;;高效液相色譜-串聯(lián)質(zhì)譜法檢測羊奶中乙酰孕激素多殘留研究[J];分析測試學(xué)報(bào);2012年10期

2 張艷;陳劍剛;馮翠霞;;液相色譜-串聯(lián)質(zhì)譜法測定牛奶中孕激素和雄激素殘留[J];中國衛(wèi)生檢驗(yàn)雜志;2013年13期

3 王玲;鄭明剛;蘭靖;劉峰;;廢水中雌激素和孕激素檢測方法[J];科技導(dǎo)報(bào);2011年09期

4 ;[J];;年期

相關(guān)重要報(bào)紙文章 前2條

1 陳飛;產(chǎn)后三個(gè)月就該避孕[N];農(nóng)村醫(yī)藥報(bào)（漢）;2005年

2 中國性學(xué)會(huì)性醫(yī)學(xué)專業(yè)委員會(huì)主任 馬曉年;迎考：如何推遲經(jīng)期？[N];健康時(shí)報(bào);2004年

相關(guān)碩士學(xué)位論文 前3條

1 甘蕾;孕激素、基質(zhì)金屬蛋白酶10、瘦素受體與妊娠期糖尿病的相關(guān)性研究[D];第三軍醫(yī)大學(xué);2015年

2 溫馨;雌激素和孕激素在松花江水體及給水處理單元的分布規(guī)律[D];哈爾濱工業(yè)大學(xué);2014年

3 黃檢英;孕激素和雌激素對AD模型大鼠海馬神經(jīng)保護(hù)作用[D];浙江大學(xué);2011年

，

本文編號(hào)：1649203