本文選題：環(huán)保防蠟劑　切入點(diǎn)：含蠟量　出處：《東北石油大學(xué)》2017年碩士論文　論文類型：學(xué)位論文

【摘要】：石油在當(dāng)今社會(huì)的發(fā)展中占據(jù)著至關(guān)重要的地位,社會(huì)的發(fā)展對(duì)石油能源的需求與日俱增。我國(guó)多數(shù)原油屬于高凝點(diǎn)原油,原油的這種物性為原油的開采與運(yùn)輸帶來了一定的困難。通過添加防蠟劑的方式改變?cè)偷牡蜏亓鲃?dòng)性,可以降低原油的開采難度,節(jié)約運(yùn)輸成本。由于目前使用的防蠟劑存在二次污染的問題,本文通過研究?jī)煞N模擬油對(duì)安全環(huán)保型防蠟劑的性能,為原油的開采與防蠟劑的研制提供一定的理論依據(jù)。通過研究溶劑對(duì)防蠟劑效果的影響得出-35#柴油具有很好的溶解性能,并且環(huán)保污染小。采用-35#柴油作為環(huán)保型防蠟溶劑,將環(huán)保型防蠟劑作用于含蠟量不同的模擬油,通過改變反應(yīng)時(shí)間、反應(yīng)溫度、加劑量來研究對(duì)防蠟劑的防蠟效果的影響。實(shí)驗(yàn)表明針對(duì)含蠟量為15%與25%的模擬油最佳反應(yīng)條件為:反應(yīng)時(shí)間為40min;反應(yīng)溫度為60℃;加劑量為300ppm。針對(duì)含蠟量為35%的模擬油最佳反應(yīng)條件為:反應(yīng)時(shí)間為40min;反應(yīng)溫度為60℃;加劑量為400ppm。將兩種防蠟劑作用于膠質(zhì)含量不同的模擬油,通過改變加劑量得出羧酸酯類防蠟劑對(duì)高膠質(zhì)含量模擬油具有較好地降凝效果,凝點(diǎn)下降26℃。將防蠟劑WI-1加入到膠質(zhì)含量不同的模擬油中,改變處理溫度與反應(yīng)溫度得出以下結(jié)論:反應(yīng)溫度對(duì)防蠟劑作用于模擬油的降粘效果具有較大程度的影響,處理溫度為65℃、反應(yīng)溫度為60℃時(shí)模擬油粘度最小。防蠟劑WI-1針對(duì)膠質(zhì)含量為16.11%的模擬油粘度可降低約40mm2/s。防蠟劑WI-1對(duì)不同膠質(zhì)含蠟量的模擬油在防蠟率的改善方面得出以下結(jié)論:加劑量為300ppm時(shí),膠質(zhì)含量介于3-5%之間防蠟劑WI-1具有最佳的防蠟效果,醋酸乙烯酯類防蠟劑在加劑量為300ppm時(shí)對(duì)模擬油-2防蠟率最高為65.9%。通過正交實(shí)驗(yàn)得出以下結(jié)論:從影響程度大小來說,加劑量反應(yīng)時(shí)間防蠟劑反應(yīng)溫度;防蠟劑PI40:EVA32:PMA復(fù)配的最佳比例為6:3:1,使用-35#柴油作為防蠟溶劑可以達(dá)到既環(huán)保又安全的目的;復(fù)配后的防蠟劑溶于-35#柴油,配制比例為6:3:1的防蠟劑FI-2降凝效果最佳,在加劑量為400ppm時(shí),凝點(diǎn)降低24℃。在反應(yīng)時(shí)間為40min,反應(yīng)溫度為60℃,加劑量為400ppm時(shí),將復(fù)配型防蠟劑FI-2即PI40:EVA32:PMA比例為6:3:1作用于油樣芳葡86-S-026時(shí)防蠟效果最佳,防蠟率最高可達(dá)到83.6%。
[Abstract]:Oil plays a vital role in the development of today's society, and the demand for petroleum energy is increasing with the development of society. Most of the crude oil in China belongs to high freezing point crude oil. This physical property of crude oil has brought some difficulties to the exploitation and transportation of crude oil. By adding a wax-proof agent to change the low temperature fluidity of crude oil, it can reduce the difficulty of crude oil exploitation. Saving transportation cost. Because of the problem of secondary pollution of the wax inhibitor used at present, this paper studies the performance of two kinds of simulated oil to the safety and environmental protection type wax inhibitor. This paper provides some theoretical basis for the exploitation of crude oil and the development of waxproof agent. By studying the influence of solvent on the effect of waxproof agent, it is concluded that the diesel oil has good solubility and little environmental pollution. By changing the reaction time and reaction temperature, the environmental antiwaxant was applied to the simulated oil with different wax content. The optimum reaction conditions for the simulated oil with wax content of 15% and 25% were as follows: reaction time 40 min, reaction temperature 60 鈩，

本文編號(hào)：1602957